SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

For a substance the name, identification number when it appears in Part 3 of Annex VI of Regulation 1272/2008, or appears in the classification & labelling inventory, or the CAS number and name. For a mixture the trade name or designation must be provided.

You can also provide any other names or synonyms for the substance or mixture.

1.2. Relevant identified uses of the substance or mixture and uses advised against

Briefly describe any relevant uses for the substance or mixture, along with any uses that you advise against.

1.3. Details of the supplier of the safety data sheet

The supplier's full address, telephone number and the email address for the person responsible for the safety data sheet.

When supplying to another country you can supply the name and full address for your representative in that county.

1.4. Emergency telephone number

A contact telephone number for emergency information on the substance or mixture, when this service is limited for any reason then this must also be given.

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

The classifications for a substance for both CLP and CHIP must be shown, currently for a mixture the CLP classifications do not need to be shown, unless labelling under CLP.

Example

CHIP	CLP
Dangerous to the Environment N, R50/53 Corrosive C, R34	Skin Corr. 1A H314 Aquatic Acute 1 H400 Aquatic Chronic 1 H410

2.2. Label elements

This area shows the hazards on the label.

For a substance you will show any hazard pictogram(s), signal word(s), hazard statement(s) and precautionary statement(s).

For a mixture if you have decided to continue labelling under the CHIP regulations you will show the appropriate symbol(s) along with their label, indication(s) of danger, Risk phrase(s) and Safety phrase(s).

The CLP pictogram(s) or CHIP symbol(s) can be in black and white or colour.

Example:

Hazard statements
H314	Causes severe skin burns and eye damage<
H410	Very toxic to aquatic life with long lasting effects.
EUH071	Corrosive to the respiratory tract.
Precautionary Statements
P260	Do not breathe dust/fume/gas/mist/vapours/spray
P273	Avoid release to the environment
P280	Wear protective gloves/protective clothing/eye protection/face protection
P301+P330+P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P391	Collect spillage

2.3. Other hazards

Information on any hazards which do not result in a classification but which may contribute to the overall hazards of the substance or mixture.

In a safety data sheet created under CLP, where you do not know if all of the substances in a mixture are not harmful to:

• human health then you must indicate this with the statement "x percent of the mixture consists of component(s) of unknown toxicity"

• the environment the statement "Contains x% of components with unknown hazards to the aquatic environment"

SECTION 3: Composition/information on ingredients

This is the only place under the regulations that you can NOT show a sub-section. On your MSDS show one of the following sections depending on if it is a single active substance or a mixture.

3.1. Substances

The chemical identity of the main constituent of the substance shall be provided by using the product identifier or one of the other means of identification given in subsection 1.1. You can also provide information on all constituents including non-classified substances.

Example

Conc. %	CAS	EINECS	Classification according to DSD	Classification according to CLP
Sodium hypochlorite, solution ... % CI active
25	7681-52-8	231-668-3	C Corrosive R34 N Dangerous for the Environment R50/53	Skin Corr. 1B H314 Aquatic Acute 1 H400 Aquatic Chronic 1 H410
Inert Dilutant
75			Not classified	Not Classified

3.2. Mixtures

Show all substances in the mixture that are hazardous and the concentration is above the lower limit. The concentration percentage for a substance can be an exact figure or a range of percentages, when a range is used the higher value is used in the calculation for how hazardous the mixture is.

Example

Conc. %	CAS	EINECS	Classification according to DSD	Classification according to CLP
Sodium hypochlorite, solution ... % CI active
25	7681-52-8	231-668-3	C Corrosive R34 N Dangerous for the Environment R50/53	Skin Corr. 1B H314 Aquatic Acute 1 H400 Aquatic Chronic 1 H410
Sodium hydroxide
5	1310-73-2	215-185-5	Xi Irritant R36	Skin Corr. 1A H314

SECTION 4: First aid measures

4.1. Description of first aid measures

Advice should be given on any immediate medical attention, the movement of the exposed individual, the removal and handling of clothing and any personal protective equipment for first aid responders. The information should be given for each route of exposure such as skin, eye, inhalation and ingestion.

4.2. Most important symptoms and effects, both acute and delayed

Summarise briefly the most important symptoms and effects, both acute and delayed, from exposure. This is usually summarised by each route of exposure.

4.3. Indication of any immediate medical attention and special treatment needed

Provide any appropriate information on clinical testing and medical monitoring for delayed effects, along with any antidotes required and any inadvisable treatment.

For some substances or mixtures it may be important to emphasise that immediate treatment should be available in the workplace.

This is usually summarised by each route of exposure.

SECTION 5: Firefighting measures

5.1. Extinguishing media

This is where you provide information on the types of suitable/unsuitable extinguishing equipment. There are two recommended headings shown in the regulations "Suitable extinguishing media" and "Unsuitable extinguishing media"

5.2. Special hazards arising from the substance or mixture

Provide any information on hazards that may arise from the combustion of the substance or mixture, like "may produce toxic fumes of carbon monoxide if burning" or "produces oxides of sulphur and nitrogen on combustion".

5.3. Advice for firefighters

Advice on any protective actions to be taken while fire fighting, like "keep containers cool with water spray" and any special protective equipment for fire fighters

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

It is recommended within the regulations to use two headings within this sub-section

For non-emergency personnel

Any advice related to spills and the release of the substance or mixture, the wearing of personal protective equipment, removal of ignition sources, sufficient ventilation, the control of dust and any emergency procedures.

For emergency responders

Any advice on the personal protective equipment to wear or not to wear for emergency responders, this includes the in house emergency team and emergency professionals.

6.2. Environmental precautions

Advice on the precautions to take in the event of an accidental spill and release of the substance or mixture, such as keeping away from drains, surface or ground water

6.3. Methods and material for containment and cleaning up

The appropriate measures on how to contain and clean-up a spill, appropriate headings might include any of the following:

Bundling, covering of drains

Capping procedures

Neutralisation techniques

Decontamination techniques

Absorbent materials

Cleaning techniques

Vacuuming techniques

Equipment required for containment/clean-up (include the use of non-sparking tools and equipment where applicable)

Give any other information relating to spills and releases, including advice on inappropriate containment or clean-up techniques.

6.4. Reference to other sections

When appropriate give reference to sections 8 and 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Provide recommendations on the safe handling and advice on general occupational hygiene for the substance or mixture.

7.2. Conditions for safe storage, including any incompatibilities

The advice given will be consistent with the physical and chemical properties described in section 9. When relevant, provide advice on specific storage requirements, manage associated risks, control of environment effects, how to maintain the integrity of the substance or mixture and any other advice.

7.3. Specific end use(s)

Detailed and operational information on the substance or mixture, the Information must be consistent with any information given elsewhere on the safety data sheet or any exposure scenarios or chemical safety report provided with the safety data sheet. When there is industry or sector specific guidance available, a detailed reference, including the source and issuing date may be made.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Any OEL/WEL limits for the substance or substances within the mixture are to be shown here.

Example

CAS	Component	WEL 8hr limit		WEL 15min limit
		ppm	mg/m3	ppm	mg/m3
7681-52-9	Sodium hypochlorite, solution ... % CI active	-	-	-	-
1310-73-2<	Sodium hydroxide	-	-	-	2.00000
Legal Basis:	EH40/2005 Workplace exposure limits

8.2. Exposure controls

Appropriate engineering controls

The description of appropriate exposure control measures that relate to the identified use(s) referred to in sub-section 1.2. This information will be sufficient to enable the employer to carry out an assessment of risk to the health and safety of workers arising from the presence of the substance or mixture in accordance with Articles 4 to 6 of directive 98/24/EC as well as in accordance with Articles 3 to 5 of Directive 2004/37/EC, where appropriate. This information will complement that already given in section 7.

Individual protection measures, such as personal protective equipment

This information shall be consistent with good occupational hygiene practices and other control measures. Where appropriate, section 5 can be referred to for specific fire/chemical personal protective equipment advice.

Eye/face protection

The type of protection equipment required based on the hazard of the substance or mixture and potential for contact.

Skin protection

Hand protection

The type of gloves to be worn when handling the substance or mixture, this will include the type of material and thickness, the typical or minimum breakthrough time and any other necessary additional hand protection measures.

Other

When it is necessary to protect other parts of the body the type and quality of personal protection equipment required.

Respiratory protection

For gases, vapours, mist or dust, the type of protective equipment to be used shall be specified based on the hazard and potential for exposure, including air-purifying respirators, specifying the proper purifying element (cartridge or canister), the adequate particulate filters and the adequate masks, or self-contained breathing apparatus.

Thermal hazards

Personal protective equipment to be worn for materials that represent a thermal hazard, special consideration shall be given to the construction of the personal protective equipment.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

The following properties will be clearly identified including, where appropriate, a reference to the test methods used and specification of the appropriate units of measurement and/or reference conditions. When you state that a particular property does not apply or there is no information available, the reasons will be given.

In the case of a mixture, the entries will state which substance the data applies to, unless it applies to the whole mixture.

• (a) Appearance:

The physical state (solid, liquid, gas) and the colour of the substance or mixture as supplied

• (b) Odour:

If an odour is perceptible, a brief description of it shall be given

• (c) Odour threshold
• (d) pH:

The pH shall be indicated of the substance or mixture as supplied or of an aqueous solution; in the latter case, the concentration shall be indicated

• (e) Melting point/freezing point;
• (f) Initial boiling point and boiling range;
• (g) Flash point;
• (h) Evaporation rate;
• (i) Flammability (solid, gas);
• (j) Upper/lower flammability or explosive limits;
• (k) Vapour pressure;
• (l) Vapour density;
• (m) Relative density;
• (n) Solubility(ies);

Indicate the liquid this applies to

• (o) Partition coefficient: n-octanol/water;
• (p) Auto-ignition temperature;
• (q) Decomposition temperature
• (r) Viscosity;
• (s) Explosive properties;
• (t) Oxidising properties.

Example

Appearance	Orange solid powder
Odour	Faint lemon smell
Odour threshold	No data
pH	Not applicable
Melting point/freezing point	No data
Initial boiling point and boiling range	No data
Flash point	No data
Evaporation rate	Not applicable
Flammability (solid, gas)	Inconclusive evidence
Upper/lower flammability or explosive limits	No data
Vapour pressure	Not applicable
Vapour density	Not applicable
Relative density	1ug particle size
Solubility(ies)	Soluble in water
Partition coefficient: n-octanol/water	No data
Auto-ignition temperature	No evidence of auto-ignition
Decomposition temperature	No data
Viscosity	Not applicable
Explosive properties	No evidence of explosive properties
Oxidising properties	No evidence of oxidising properties

9.2. Other information

Any other physical and chemical parameters will be indicated, such as miscibility, fat solubility, conductivity or gas group. Any appropriate and available safety information on redox potential, radical formation potential and photocatalytic properties will be shown.

SECTION 10: Stability and reactivity

When you state that a particular property does not apply or there is no information available, the reasons will be given.

10.1. Reactivity

Describe the reactivity hazards of the substance or mixture, giving specific test data for the substance or mixture as a whole, when available. The information may be based on general data for the class or family of substance or mixture, if the data adequately represents the anticipated hazards.

If the data for a mixture is not available, then data on the substances in the mixture will be provided, you should also take into account any incompatibilities that the substance or mixture might be exposed to during transportation and storage.

10.2. Chemical stability

Indicate how stable or unstable the substance or mixture is under normal ambient and anticipated storage and handling conditions of temperature and pressure. Describe any stabilisers that are or may need to be used to maintain the chemical stability, and, any safety significance of change in the physical appearance.

10.3. Possibility of hazardous reactions

Describe the conditions under which any hazardous reactions might occur, and, when relevant if the substance or mixture will react or polymerise, releasing excess pressure or heat or creating other hazardous conditions.

10.4. Conditions to avoid

List and if appropriate give a brief description of measures to be taken to manage associated hazards for conditions such as temperature, pressure, light, shock, static discharge, vibration or other physical stresses.

10.5. Incompatible materials

List the families of substances or mixtures or substances, like water, oxidising agents, air or acids, that the substance or mixture will react with to produce a hazardous situation, such as a release of toxic or flammable materials, explosion or excessive heat.

10.6. Hazardous decomposition products

List any known or anticipated hazardous decomposition products produced as a result of use, storage spill and heating. Hazardous combustion products will be listed in section 5.

SECTION 11: Toxicological information

When you state that a particular property does not apply or there is no information available, the reasons will be given.

11.1. Information on toxicological effects

For substances show:

• a) Acute toxicity
• b) Skin corrosion/irritation
• c) Serious eye damage/irritation
• d) Respiratory or skin sensitisation
• e) Germ call Mutagenicity
• f) Carcinogenicity
• g) Reproductive toxicity
• h) STOT-single exposure
• i) STOT-repeated exposure
• j) Aspiration hazard

For mixtures:

• a) Acute toxicity
• b) Irritation
• c) Corrosively
• d) Sensitisation
• e) Repeated does toxicity
• f) Carcinogenicity
• g) Mutagenicity
• h) Toxicity for reproduction

• Give information on the likely routes of exposure
• Explain the symptoms related to the physical, chemical and toxicological characteristics
• Give information on the delayed and immediate effects as well as chronic effects from short and long term exposure
• Explain any interactive effects
• Explain the absence of specific data
• Give mixture versus substance information
• Give any other information

SECTION 12: Ecological information

The information in this section shall be consistent with the information provided in the registration and/or in the chemical safety report where required, and with the classification of the substance or mixture.

When you state that a particular property does not apply or there is no information available, the reasons will be given.

12.1. Toxicity

When available, provide information on toxicity, using there is data from tests performed on aquatic and/or terrestrial organisms. This includes relevant available data on aquatic toxicity both acute and chronic for fish, crustaceans, algae and other aquatic plants. In addition, toxicity data on soil micro and macro-organisms and other environmentally relevant organisms, such as birds, bees and plants are to be given. When the substance or mixture has an effect on micro-organisms, the impact on sewage treatment plants will be mentioned.

12.2. Persistence and degradability

Test results relevant to assess persistence and degradability shall be given where available. If degradation half- lives are quoted it must be indicated whether these half lives refer to mineralisation or to primary degradation. The potential of the substance or certain substances in a mixture to degrade in sewage treatment plants shall also be mentioned.

When available and appropriate this information shall be given for each individual substance in the mixture which is required to be shown in section 3.

12.3. Bioaccumulative potential

Test results relevant to assess the bio accumulative potential shall be given. This shall include reference to the octanol-water partition coefficient (Kow) and bio concentration factor (BCF), if available.

When available and appropriate this information shall be given for each individual substance in the mixture which is required to be shown in section 3.

12.4. Mobility in soil

The potential for mobility in soil shall be given where available. Information on mobility can be determined from relevant mobility data such as adsorption studies or leaching studies, known or predicted distribution to environmental compartments, or surface tension. For example, Koc values can be predicted from octanol/water partition coefficients (Kow). Leaching and mobility can be predicted from models.

When available and appropriate this information shall be given for each individual substance in the mixture which is required to be shown in section 3.

12.5. Results of PBT and vPvB assessment

When a chemical safety report is required, the results of the PBT and vPvB assessment will be given.

12.6. Other adverse effects

Information on any other environmental adverse effects is to be given here.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

This section will describe the proper waste management of the substance or mixture along with its container. This information will complement the information given in section 8.

When there is a chemical safety report the information here will be consistent with the identified uses in the chemical safety report and any exposure scenarios.

SECTION 14: Transport information

There is no requirement under the EU regulations to show the transport symbols here.

14.1. UN number

This is the four figure identification number for the substance or mixture. The number is preceded by the letters "UN". In the USA this is known as the DOT number, in most instances the numbers mean the same.

14.2. UN proper shipping name

This is the description that is linked to the UN number.

14.3. Transport hazard class(es)

Show the transport hazard class and subsidiary classes for the substance or mixture that the UN number is linked to.

14.4. Packing group

When applicable the packing group for the substance or mixture will be shown here.

14.5. Environmental hazards

It shall be indicated whether the substance or mixture is environmentally hazardous according to the criteria of the UN Model Regulations (as reflected in the IMDG Code, ADR, RID and ADN) and/or a marine pollutant according to the IMDG Code. If authorised or intended for carriage by inland waterways in tank-vessels, it shall be indicated whether the substance or mixture is environmentally hazardous in tank-vessels only according to ADN.

14.6. Special precautions for user

Describe any information on special precautions for the substance or mixture which the user must comply with or be aware of in connection with the transport or conveyance of the substance or mixture either within or outside his premises.

In this section you could have information like Tunnel Codes and the EAC plate code.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

This section only applies when cargos are intended to be carried in bulk according to the following International Maritime Organisation instruments.

Example

14.1 UN number	1274
14.2 UN proper shipping name	n-PROPANOL (PROPYL ALCOHOL, NORMAL)
14.3 Transport hazard class(es)	3
14.4 Packing group	II
14.5 Environmental hazards	No data
14.6 Special precautions for user	EMS: F-E, S-D EAC: 2YE TUNNEL: D/E
14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code	Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Information regarding relevant Community safety, health and environmental provisions (for example, Seveso category/named substances in Annex I of Council Directive 96/82/EC ( 5 )) or national information on the regulatory status of the substance or mixture (including the substances in the mixture), including advice regarding action that should be taken by the recipient as a result of these provisions shall be provided. Where relevant the national laws of the relevant Member States which implement these provisions and any other national measures that may be relevant shall be mentioned.

15.2. Chemical safety assessment

Indicate if a chemical safety assessment has been carried out.

SECTION 16: Other information

Include information here that is not shown in section 1 to 15, such as

• the revision date and what data has been changed

• key references and sources for the data

• For a mixture the methods of evaluating information referred to in Article 9 of Regulation (EC) No. 1272/2008 that was used for the purpose of classification

• List relevant R phrases and hazard statements that have only had their codes used in section 2 - 15, there is nothing to stop you listing all used codes.

• Advice on the training appropriate for workers to ensure protection of human health and the environment

Section 1. Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier:

Fruit1, Orange

1.2 Relevant identified uses of the substance or mixture and uses advised against:

Used as food. Advised not to be used as a football

1.3 Details of the supplier of the Safety data sheet 1.4. Emergency telephone number:

+44 1999 564999 (0900 to 0930 GMT Monday Only)

Section 2. Hazards identification

2.1. Classification of the substance or mixture: 2.2. Label elements

WARNING

2.3. Other hazards

Contains 34% of components with unknown hazards to the environment

Section 3. Composition/information on ingredients

3.2 Mixtures

Section 4. First aid measures

4.1. Description of first aid measures


4.2. Most important symptoms and effects, both acute and delayed


4.3. Indications of any immediate medical attention and special treatment

Section 5. Fire fighting measures

5.1. Extinguishing media 5.2. Special hazards arising from the substance or mixture

Combustion may generate hazardous gasses

5.3. Advice for fire fighters

Wear breathing apparatus.

Section 6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures 6.2. Environmental precautions:

Take precautions to ensure product does not contaminate ground or enter the drainage system

6.3. Methods and material for containment and cleaning up:

Do not allow the product to enter drains. Do not flush into surface water. Do not allow the product to contaminate sub-soil. Prevent further spillage if safe to do so.

6.4. Reference to other sections

Refer top section 8 for appropriate protective equipment and section 13 for disposal information.

Section 7. Handling and storage

7.1. Precautions for safe handling

Avoid contact with skin and eyes. Do not breathe dust. Work using a suitable extraction/ventilation system. Wash hands and face thoroughly after working with material. Contaminated clothing should be removed and washed before re-use.

7.2. Conditions for safe storage, including any incompatibilities

The mixture is to be store in a cool dry place (below 25 C) in unopened original packing. There are no known incompatibilities.

7.3. Specific end use(s)

Used as a food additive.

Section 8. Exposure controls/personal protection

8.1. Control parameters 8.2. Exposure controls

   

Section 9. Physical and chemical properties

9.1 Information on basic physical and chemical properties
9.2. Other information
No data

Section 10. Stability and reactivity

10.1 Reactivity

Incompatible with heat, oxidising agents and moisture

10.2 Chemical stability

Stable

10.3 Possibility of hazardous reactions

None known

10.4 Conditions to avoid

Heat, direct or sunlight

10.5 Incompatible materials

Oxidising agents

10.6 Hazardous decomposition products

None known

Section 11. Toxicological information

11.1 Information on toxicological effects

Section 12. Ecological information

Section 13. Disposal considerations

13.1. Waste treatment methods

Chemical residues are generally classified as special waste and as such, are covered by regulations which vary according to location. Contact your local waste disposal authority for advice or pass to a chemical company.

Section 14. Transport information

14.1. UN number
14.2. UN proper shipping name
14.3. Transport hazard class(es)
14.4. Packing group
14.5. Environmental hazards
14.6. Special precautions for user
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Section 15. Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.2. Chemical safety assessment

No chemical assessment available

Section 16. Other information